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金钢板磷化是常用的前处理技术,原理上应属于化学转化膜处理。工程上应用主要是钢铁件表面磷化,但有色金属如铝、锌件也可应用磷化。

The phosphating of steel plate is a kind of commonly used pretreatment technology. Application of the project is mainly on the surface of iron and steel phosphating, but non-ferrous metals such as aluminum, zinc parts can also be applied phosphating.

磷化原理:

Phosphating principle:

工件(钢铁或铝、锌件)浸入磷化液(某些酸式磷酸盐为主的溶液),在表面沉积形成不溶于水的结晶型磷酸盐转化膜的过程,称之为磷化。

The workpiece (steel or aluminum, zinc) into the phosphating solution (some acid phosphate based solution), the surface of the formation of water insoluble crystalline phosphate conversion film.

把金属放入含有锰、铁、锌的磷酸盐溶液中进行化学处理,使金属表面生成一层难溶于水的磷酸盐保护膜的方法,叫做金属的磷酸盐处理。磷化膜层为微孔结构,与基体结合牢固,具有良好的吸附性、润滑性、耐蚀性、不粘附熔融金属(Sn、Al、Zn)性及较高的电绝缘性等。

The process of chemical treatment of a metal into a solution containing manganese, iron and zinc to form a layer of insoluble phosphate protective film on the surface of the metal. The phosphating film is a microporous structure, which is firmly bonded with the substrate, and has good adsorption property, lubricity, corrosion resistance, non adherence to molten metal (Sn, Al, Zn) and high electrical insulation.

磷化分类:

Phosphating classification:

按合金钢板处理温度分:高温型(75-100℃,能耗大,磷化物沉积多,形成的磷化膜厚度达10-30g/㎡)、中温型(50-75℃,处理时间5-15min,磷化膜厚度达1 -8g/㎡)、低温型(30-50℃)和常温型(10-30℃,节省能源,使用方便,除加氧化剂外还加促进剂,能耗小,但溶液配制较复杂,膜厚度达0.2-7g/㎡)。

According to the alloy steel plate processing temperature: high temperature (75-100 DEG C, high energy consumption, multi phosphating film thickness phosphide deposition, the formation of up to 10-30g/ meters) and medium temperature (50-75 DEG C, processing time 5-15min, phosphating film thickness of 1 -8g/ m) and low temperature (30-50 DEG C) and room temperature (10-30 DEG C, save energy, easy to use, in addition to oxidants and accelerant, the energy consumption is small, but the solution is complicated, the membrane thickness of 0.2-7g/ m).

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按磷化液成分分:锌系磷化、锌钙系磷化、锌锰系磷化、铁系磷化、锰系磷化和复合磷化等。

According to the composition of the phosphating solution: zinc series phosphating, zinc calcium series phosphating, zinc manganese series phosphating, iron phosphating, manganese phosphating and composite phosphating.

按磷化处理方法分:化学磷化、电化学磷化。

According to the phosphating treatment methods: chemical phosphating, electrochemical phosphating.

按磷化膜质量分:重量级(膜重7.5g/㎡以上)、次重量级(膜重4.6-7.5g/㎡)、轻量级(膜重1.1-4.5g/㎡)和次轻量级(膜重0.2-1g/㎡)。

According to the quality of the phosphating film is divided into: (more than 7.5g/ square meters heavyweight film weight), heavyweight (film 4.6-7.5g/ m), lightweight (film 1.1-4.5g/ m) and lightweight (film 0.2-1g/ m).

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